

Proving plagiarism after the fact can be very labor intensive. You can take a low tech or a high tech approach to determining if a paper is plagiarized:
Low Tech
High Tech
A succinct Comparison of Plagiarism Detection Services has been done by librarians at Eastern Oregon and Western Oregon Universities.
A more extended discussion of the topic of plagiarism detection sevices and software can be found at Virtual Academic Integrity Laboratory at the Center for Intellectual Property at the University of Maryland. It includes a discussion of factors to be considered in deciding to use a detection tool and the limitations of the tools.
Actual tests of several of these detection tools were conducted by a librarian and a technology specialist at Colorado College and summarized in Downloading Detectives: Searching for On-Line Plagiarism. Their basic conclusions were that:
One of the more popular detection tools, turnitin.com, has been the subject of some discussion on the question of whether it violates student rights. The issue was discussed in the May 17, 2002 issue of the Chronicle of Higher Education in an article by Andrea Foster entitled Plagiarism-Detection Tool Creates a Legal Quandary